Periodic Table

Rhodium

Transition Metal

Quick Facts about Rhodium

Ru
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +3- common oxidation states in compounds
  • FCC- crystal structure, atomic arrangement in solid form
Pd

Rhodium (Rh) is element 45 on the periodic table. Atomic mass of Rh: 102.9100 u. Rh is in period 5, group 9. Melting point of Rh: 2237.00 K.Density of Rh: 12.41 g/cm³.

Why Rhodium Matters

Rhodium in everyday life and industry

In Your Home

  • Three-way catalytic converters in cars require rhodium
  • Rhodium plating gives white gold and silver jewelry a bright finish
  • Laboratory crucibles for high-temperature chemistry use rhodium

Industry Uses

IndustryOptical mirrors for lasers sometimes use rhodium coatings

In Your Body

✗ Not essential

Rhodium has no biological role in humans. Some rhodium compounds are being studied for cancer treatment. Rhodium compounds can cause skin and eye irritation.

Safety: The metal is generally considered non-toxic

Discovery of Rhodium

Discovered by William Wollaston in England, 1803

Name origin: Greek: rhodon (rose). Its salts give a rosy solution.

History & Events

1803
Named from Greek 'rhodon' meaning rose, for its rose-colored compounds
1803
Discovered by William Hyde Wollaston in 1803
1803
Extracted from platinum ore from South America
1803
Became the most expensive precious metal several times due to catalytic converter demand

About Rhodium

Silvery white metallic transition element. Found with platinum and used in some platinum alloys. Not attacked by acids, dissolves only in aqua regia. Discovered in 1803 by W.H. Wollaston.

Atomic Properties of Rh

Atomic Number of Rh
45
Atomic Mass of Rh
102.9100 u
Electron Configuration
[Kr] 4d8 5s1
Electronegativity
2.28
Block
d-block
Group
9
Period
5

Physical Properties of Rh

Phase (STP)
solid
Melting Point of Rh
2237.00 K
Boiling Point of Rh
3968.00 K
Density of Rh
12.4100 g/cm3

Thermal Properties

Heat of Fusion
21.80 kJ/mol
Heat of Vaporization
494.00 kJ/mol
Specific Heat
0.24 J/g·K
Molar Heat Capacity
24.98 J/mol·K
Thermal Conductivity
150.00 W/m·K

Atomic Radii

Calculated
135 pm
Covalent
125 pm
Van der Waals
210 pm
Metallic
125 pm

Common Misconceptions

Wrong:Rhodium, rhodonite, and rhododendron are related.
Correct:All three come from Greek 'rhodon' (rose) due to their color, but rhodium is a metal, rhodonite a mineral, and rhododendron a plant.
Wrong:Rhodium plating on jewelry is permanent.
Correct:Rhodium plating on white gold wears off in 1-3 years with regular wear. Re-plating costs $50-100 and is a routine jewelry service.
Wrong:Rhodium is called 'white' because the metal is white.
Correct:The metal is silvery-white, but it's named for the rose-red color of its compounds in solution.

Isotopes of Rhodium

Rhodium has 1 naturally occurring isotope, plus 2 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
10345Rh (Rh-103)Rhodium-103 isotope102.905498100.00%
10545Rh (Rh-105)Rhodium-105 isotope104.9056940%35.36 hoursβ⁻
10645Rh (Rh-106)Rhodium-106 isotope105.9072870%29.8 secondsβ⁻

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Rhodium have important real-world applications in science and industry.

Medical Applications

The beta particles of 105Rh (with a half-life of about 35 h) are used in target radiotherapy to kill cancer cells or cause cancer cell sterilization [334]. The gamma rays from 105Rh enable in vivo tracking during radiotherapy [334]. 105Rh has been used in the treatment of bone pain (Fig. IUPAC.45.1) [334], [337]. Ocular brachytherapy currently is performed using 125I (with a half-life of about 59 days) or 106Rh (with a half-life of about 30 s) seeds [338]. Brachytherapy can allow a good spatial dose distribution over the ocular tumor with lower radiation on adjacent tissues. In the case of irradiation of the eyeball with 106Rh, 80 percent of the dose has been absorbed within a depth of 5.2 mm and 90 percent has been absorbed within 7.2 mm (Fig. IUPAC.45.2). This limits the application of 106Rh; however, when 106Rh can be used, the radiation dose can be lower, which is preferred.

Abundance

Earth's Crust
1.00 μg/kg

Uses

Used as a coating to prevent wear on high quality science equipment and with platinum to make thermocouples.

Sources

Obtained as a by-product of nickel production.

Geochemistry

Goldschmidt
siderophile
Geochemical Class
noble metal

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