Periodic Table

Silver

Transition Metal

Quick Facts about Silver

Pd
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +1- common oxidation states in compounds
  • FCC- crystal structure, atomic arrangement in solid form
Cd

Silver (Ag) is element 47 on the periodic table. Atomic mass of Ag: 107.8700 u. Ag is in period 5, group 11. Melting point of Ag: 1234.93 K.Density of Ag: 10.49 g/cm³.

Why Silver Matters

The best conductor of electricity—and humanity's first antibiotic

In Your Home

  • Silverware and jewelry
  • Mirrors (silver coating behind glass)
  • Antibacterial bandages and wound dressings
  • Silver-ion water purifiers

Industry Uses

ElectronicsBest electrical conductor—used in high-end contacts and switches
SolarSilver paste conducts current in solar panels
PhotographySilver halides in traditional film (declining)
MedicineSilver sulfadiazine treats burns, silver nanoparticles kill bacteria

In Your Body

✗ Not essential

Not essential for humans. Antimicrobial properties have been known since ancient times—silver vessels kept water fresh. Colloidal silver supplements are unproven and potentially harmful.

Safety: Low toxicity. Chronic exposure causes argyria (permanent blue-gray skin). Silver ions are toxic to bacteria.

Discovery of Silver

Discovered by Known to the ancients.,

Name origin: Anglo-Saxon: siolful, (silver); symbol from Latin: argentium.

History & Events

3000 BCE
Ancient Mining
Silver mining began in Anatolia (Turkey), used for trade and currency
1545
Potosí Silver
Spanish discovery of Potosí (Bolivia) produced 60% of world's silver, funding an empire
1840
Photography Born
Fox Talbot's calotype process used silver compounds, launching photography

Why "Ag" for Silver?

AgArgentum(Latin)

The symbol Ag comes from "Argentum," the Latin word for silver, related to the Greek "argyros" meaning "white" or "shining." Argentina is named after this element due to early silver mining.

About Silver

White lustrous soft metallic transition element. Found in both its elemental form and in minerals. Used in jewellery, tableware and so on. Less reactive than silver, chemically.

Atomic Properties of Ag

Atomic Number of Ag
47
Atomic Mass of Ag
107.8700 u
Electron Configuration
[Kr] 4d10 5s1
Electronegativity
1.93
Block
d-block
Group
11
Period
5

Physical Properties of Ag

Phase (STP)
solid
Melting Point of Ag
1234.93 K
Boiling Point of Ag
2435.00 K
Density of Ag
10.4900 g/cm3

Thermal Properties

Heat of Fusion
11.95 kJ/mol
Heat of Vaporization
254.10 kJ/mol
Specific Heat
0.23 J/g·K
Molar Heat Capacity
25.35 J/mol·K
Thermal Conductivity
429.00 W/m·K

Atomic Radii

Calculated
160 pm
Covalent
128 pm
Van der Waals
211 pm
Metallic
134 pm

Common Misconceptions

Wrong:Silver kills werewolves and vampires.
Correct:This is folklore. Silver's real 'magic' is antimicrobial—it kills bacteria, fungi, and some viruses.
Wrong:Colloidal silver is a cure-all.
Correct:No proven medical benefits for internal use. FDA warns against it. Can cause permanent skin discoloration.
Wrong:Sterling silver is pure silver.
Correct:Sterling is 92.5% silver + 7.5% copper for strength. Pure silver (99.9%) is too soft for most uses.

Isotopes of Silver

Silver has 2 naturally occurring isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
10747Ag (Ag-107)Silver-107 isotope106.905091651.84%
10947Ag (Ag-109)Silver-109 isotope108.904755348.16%

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Silver have important real-world applications in science and industry.

Geochronology & Dating

The amount ratio n(107Pd)/n(107Ag) is used in geochronology to date major events in the Solar System [344], [345], [346], [347], [348], [353]. Although 107Ag is naturally occurring, it is also the daughter product by beta decay of 107Pd. If both excess 107Ag and 107Pd are present in a sample of extraterrestrial origin, then the material would have formed sometime after 107Pd decayed (i.e. sometime after the 6.5-million-year half-life of 107Pd). The n(107Pd)/n(107Ag) amount ratio can be measured to help determine when the 107Pd decay process began and determine how much time has elapsed since the material was formed.

Industrial Applications

107Ag is being studied as a possible target for cyclotron production of 103Pd (with a half-life of 17 days) via the 107Ag (p, α n) 103Pd reaction. 103Pd releases X-rays and Auger electrons at the rate of about 80 X-rays and 186 Auger electrons per 100 decays of 103Pd, which makes this isotope an ideal candidate for internal radiotherapy for the treatment of cancers. The production of this isotope in a no-carrier form (not formed in another solution) is important for its medical uses. By using neutrons, photons, and charged particles to force reactions with isotopes of a higher mass number than 103, 103Pd will occur in a fraction of those reactions. The most common methods of 103Pd production use targets of rhodium or other isotopes of palladium. However, 107Ag has also been studied as a feasible option [349], [354]. 109Ag is used to produce the gamma reference source 110mAg to help calibrate gamma detectors [349], [354].

Abundance

Earth's Crust
75.00 μg/kg
Seawater
4.00×10-5 mg/L

Uses

Used in alloys for jewelry and in other compounds for photography. It is also a good conductor, but expensive.

Sources

Found in ores called argentite (AgS), light ruby silver (Ag3AsS3), dark ruby silver(Ag3SbS3) and brittle silver.

Geochemistry

Goldschmidt
chalcophile

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