Periodic Table

Chromium

Transition Metal

Quick Facts about Chromium

V
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +6, +3, +2- common oxidation states in compounds
  • BCC- crystal structure, atomic arrangement in solid form
Mn

Chromium (Cr) is element 24 on the periodic table. Atomic mass of Cr: 51.9960 u. Cr is in period 4, group 6. Melting point of Cr: 2180.00 K.Density of Cr: 7.15 g/cm³.

Why Chromium Matters

The element that makes stainless steel stainless and chrome shine

In Your Home

  • Stainless steel appliances and cutlery
  • Chrome-plated faucets and fixtures
  • Some leather tanning
  • Green glass bottles

Industry Uses

SteelStainless steel contains 10-30% chromium
PlatingDecorative and hard chrome plating
PigmentsChrome yellow and green pigments
AerospaceSuperalloys for jet engines

In Your Body

✗ Not essential

Chromium was long described as an essential nutrient, but current evidence has not established an essential biological role in humans.

Safety: Chromium toxicity depends strongly on oxidation state and exposure. Hexavalent chromium (Cr⁠6+) compounds are toxic and carcinogenic; trivalent chromium (Cr⁠3+) is generally less toxic but is not simply harmless at every dose.

Discovery of Chromium

Discovered by Louis Vauquelin in France, 1797

Name origin: Greek: chrôma (color).

History & Events

1797
Discovery
Louis Nicolas Vauquelin discovered chromium in Siberian red lead ore
1913
Stainless Steel
Harry Brearley invented stainless steel in Sheffield, England
1996
Erin Brockovich Case
PG&E settled $333 million for hexavalent chromium contamination

About Chromium

Hard silvery transition element. Used in decorative electroplating. Discovered in 1797 by Vauquelin.

Atomic Properties of Cr

Atomic Number of Cr
24
Atomic Mass of Cr
51.9960 u
Electron Configuration
[Ar] 3d5 4s1
Electronegativity
1.66
Block
d-block
Group
6
Period
4

Physical Properties of Cr

Phase (STP)
solid
Melting Point of Cr
2180.00 K
Boiling Point of Cr
2944.00 K
Density of Cr
7.1500 g/cm3

Thermal Properties

Heat of Fusion
21.00 kJ/mol
Heat of Vaporization
342.00 kJ/mol
Specific Heat
0.45 J/g·K
Molar Heat Capacity
23.35 J/mol·K
Thermal Conductivity
93.90 W/m·K

Atomic Radii

Calculated
140 pm
Covalent
122 pm
Van der Waals
206 pm
Metallic
119 pm

Common Misconceptions

Wrong:All chromium is dangerous.
Correct:Hexavalent chromium (Cr⁠6+) compounds are much more hazardous than trivalent chromium (Cr⁠3+). Current evidence does not establish chromium as an essential human nutrient, and safety still depends on dose and exposure.
Wrong:Chrome and chromium are different.
Correct:Chrome is just short for chromium. 'Chrome plating' means chromium plating.
Wrong:Stainless steel can't rust.
Correct:Stainless steel resists corrosion but can rust under certain conditions (low oxygen, high chloride).

Isotopes of Chromium

Chromium has 4 naturally occurring isotopes, plus 1 notable radioactive isotope.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
5024Cr (Cr-50)Chromium-50 isotope49.946041834.345%
5124Cr (Cr-51)Chromium-51 isotope50.94476740%27.7 daysEC
5224Cr (Cr-52)Chromium-52 isotope51.9405062383.79%
5324Cr (Cr-53)Chromium-53 isotope52.940648159.501%
5424Cr (Cr-54)Chromium-54 isotope53.938879162.365%

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Selected uses of notable Chromium isotopes.

Cr-51

Red blood cell labeling; spleen function studies; diagnostic nuclear medicine

Applications reference: IUPAC Isotopes Matter and NIH PubChem.

Abundance

Earth's Crust
102.0 mg/kg
Seawater
3.00×10-4 mg/L

Uses

Used to make stainless steel. It gives the color to rubies and emeralds. Iron-nickel-chromium alloys in various percentages yield an incredible variety of the most important metals in modern technology.

Occurrence and Production

Chromite [Fe,Mg(CrO⁠4)] is its most important mineral. Produced commercially by heating its ore in the presence of silicon or aluminium.

Geochemistry

Goldschmidt
litophile
Geochemical Class
first series transition metal

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