Periodic Table

Cobalt

Transition Metal

Quick Facts about Cobalt

Fe
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +3, +2- common oxidation states in compounds
  • HEX- crystal structure, atomic arrangement in solid form
Ni

Cobalt (Co) is element 27 on the periodic table. Atomic mass of Co: 58.9330 u. Co is in period 4, group 9. Melting point of Co: 1768.00 K.Density of Co: 8.90 g/cm³.

Why Cobalt Matters

The blue pigment element now powering electric vehicles

In Your Home

  • Lithium-ion batteries (many contain cobalt)
  • Blue glass and ceramics
  • Vitamin B12 supplements
  • Some rechargeable tool batteries

Industry Uses

BatteryLithium cobalt oxide in phone and EV batteries
AerospaceSuperalloys for jet engine turbines
MedicalCobalt-60 for cancer radiation therapy
PigmentsCobalt blue, prized since ancient times

In Your Body

✓ Essential for life

Essential as part of vitamin B12 (cobalamin). Only vitamin containing a metal. Required for red blood cell formation and neurological function.

Safety: Excessive cobalt can cause 'cobalt cardiomyopathy' (heart damage). Cobalt-60 is radioactive. Occupational exposure is regulated.

Discovery of Cobalt

Discovered by George Brandt in Sweden, 1739

Name origin: German: kobold (goblin).

History & Events

1735
Discovery
Georg Brandt isolated cobalt, proving blue glass pigment wasn't from bismuth
1948
Vitamin B12 Structure
Dorothy Hodgkin determined B12 structure with cobalt center, winning 1964 Nobel Prize
2018
Cobalt Crisis
EV demand caused cobalt price spike, raising concerns about Congo mining

About Cobalt

Light grey transition element. Some meteorites contain small amounts of metallic cobalt. Generally alloyed for use. Mammals require small amounts of cobalt salts. Cobalt-60, an artificially produced radioactive isotope of Cobalt is an important radioactive tracer and cancer-treatment agent. Discovered by G. Brandt in 1737.

Atomic Properties of Co

Atomic Number of Co
27
Atomic Mass of Co
58.9330 u
Electron Configuration
[Ar] 3d7 4s2
Electronegativity
1.88
Block
d-block
Group
9
Period
4

Physical Properties of Co

Phase (STP)
solid
Melting Point of Co
1768.00 K
Boiling Point of Co
3200.00 K
Density of Co
8.9000 g/cm3

Thermal Properties

Heat of Fusion
15.48 kJ/mol
Heat of Vaporization
389.10 kJ/mol
Specific Heat
0.42 J/g·K
Molar Heat Capacity
24.81 J/mol·K
Thermal Conductivity
100.00 W/m·K

Atomic Radii

Calculated
135 pm
Covalent
111 pm
Van der Waals
200 pm
Metallic
116 pm

Common Misconceptions

Wrong:Cobalt blue is made from copper.
Correct:Cobalt blue (CoAl⁠2O⁠4) has been prized since antiquity. The similar-sounding 'copper' is unrelated.
Wrong:All lithium batteries contain cobalt.
Correct:Many do (LCO, NMC), but LFP (lithium iron phosphate) batteries are cobalt-free alternatives.
Wrong:Cobalt mining is ethical everywhere.
Correct:Over 60% of cobalt comes from DRC, where child labor and unsafe conditions are documented problems.

Isotopes of Cobalt

Cobalt has 1 naturally occurring isotope, plus 3 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
5727Co (Co-57)Cobalt-57 isotope56.93629140%271.8 daysEC
5827Co (Co-58)Cobalt-58 isotope57.93575280%70.86 daysEC, β⁺
5927Co (Co-59)Cobalt-59 isotope58.93319429100.00%
6027Co (Co-60)Cobalt-60 isotope59.93381630%5.27 yearsβ⁻, γ

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Selected uses of notable Cobalt isotopes.

Co-57

Mössbauer spectroscopy; gamma ray source for calibration; nuclear medicine research

Co-58

PET imaging; calibration source; nuclear physics research

Co-60

Cancer radiotherapy; food irradiation and sterilization; industrial radiography

Applications reference: IUPAC Isotopes Matter and NIH PubChem.

Abundance

Earth's Crust
25.0 mg/kg
Seawater
2.00×10-5 mg/L

Uses

Used in many hard alloys; for magnets, ceramics and special glasses. Remains hard up to 982°C. Radioactive cobalt-60 is used in cancer therapy.

Occurrence and Production

Occurs in compounds with arsenic, oxygen and sulfur as in cobaltine (CoAsS) and linneite (Co3S4). Pure cobalt is obtained as a byproduct of refining nickel, copper and iron.

Geochemistry

Goldschmidt
siderophile
Geochemical Class
first series transition metal

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