Periodic Table

Manganese

Transition Metal

Quick Facts about Manganese

Cr
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +7, +4, +3, +2- common oxidation states in compounds
  • CUB- crystal structure, atomic arrangement in solid form
Fe

Manganese (Mn) is element 25 on the periodic table. Atomic mass of Mn: 54.9380 u. Mn is in period 4, group 7. Melting point of Mn: 1519.00 K.Density of Mn: 7.21 g/cm³.

Why Manganese Matters

The element that makes steel strong and batteries work

In Your Home

  • Steel products (cars, appliances)
  • Alkaline batteries (contains MnO⁠2)
  • Some vitamins and supplements
  • Purple-tinted glass

Industry Uses

SteelRemoves sulfur and adds strength: no steel without manganese
BatteryManganese dioxide in alkaline and lithium batteries
ChemicalPotassium permanganate for water treatment
Aluminum3003 aluminum alloy contains manganese

In Your Body

✓ Essential for life

Essential for bone formation, metabolism, and antioxidant enzymes. Needed for photosynthesis (oxygen-evolving complex). Your body contains about 10-20mg.

Safety: Chronic inhalation causes 'manganism', with Parkinson's-like symptoms. Dietary manganese is safe.

Discovery of Manganese

Discovered by Johann Gahn in Sweden, 1774

Name origin: Latin: magnes (magnet); Italian: manganese.

History & Events

1774
Discovery
Johan Gottlieb Gahn isolated manganese metal by heating pyrolusite with carbon
1856
Steel Revolution
Robert Mushet added manganese to Bessemer steel, solving brittleness problem
1866
Dry Cell Battery
Georges Leclanché invented the manganese dioxide battery

About Manganese

Grey brittle metallic transition element. Rather electropositive, combines with some non-metals when heated. Discovered in 1774 by Scheele.

Atomic Properties of Mn

Atomic Number of Mn
25
Atomic Mass of Mn
54.9380 u
Electron Configuration
[Ar] 3d5 4s2
Electronegativity
1.55
Block
d-block
Group
7
Period
4

Physical Properties of Mn

Phase (STP)
solid
Melting Point of Mn
1519.00 K
Boiling Point of Mn
2334.00 K
Density of Mn
7.2100 g/cm3

Thermal Properties

Heat of Fusion
13.40 kJ/mol
Heat of Vaporization
221.00 kJ/mol
Specific Heat
0.48 J/g·K
Molar Heat Capacity
26.32 J/mol·K

Atomic Radii

Calculated
140 pm
Covalent
119 pm
Van der Waals
205 pm
Metallic
118 pm

Common Misconceptions

Wrong:Manganese and magnesium are related.
Correct:Despite similar names and both being essential, they're completely different elements with different properties.
Wrong:Steel can be made without manganese.
Correct:Virtually all steel contains manganese; it removes harmful sulfur and oxygen during production.
Wrong:Manganese is only for industrial use.
Correct:Manganese is essential for human health, involved in bone formation and enzyme function.

Isotopes of Manganese

Manganese has 1 naturally occurring isotope, plus 3 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
5125Mn (Mn-51)Manganese-51 isotope50.94821080%46.2 minutesβ⁺, EC
5225Mn (Mn-52)Manganese-52 isotope51.94556550%5.59 daysEC, β⁺
5325Mn (Mn-53)Manganese-53 isotope52.94129010%3.7 million yearsEC
5525Mn (Mn-55)Manganese-55 isotope54.93804391100.00%

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Selected uses of notable Manganese isotopes.

Mn-51

PET imaging tracer; short-lived positron emitter

Mn-52

PET imaging; blood volume studies; manganese metabolism research

Mn-53

Cosmochronology; early solar system dating; extinct radionuclide studies

Applications reference: IUPAC Isotopes Matter and NIH PubChem.

Abundance

Earth's Crust
950.0 mg/kg
Seawater
2.00×10-4 mg/L

Uses

Used in steel, batteries and ceramics. The steel in railroad tracks can contain as much as 1.2% manganese. It is crucial to the effectiveness of vitamin B1.

Occurrence and Production

Most abundant ores are pyrolusite (MnO⁠2), psilomelane [(Ba,H⁠2O)2Mn5O⁠10] and rhodochrosite (MnCO⁠3). Pure metal produced by mixing MnO⁠2 with powered Al and ignited in a furnace.

Geochemistry

Goldschmidt
siderophile
Geochemical Class
first series transition metal

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