Periodic Table

Nickel

Transition Metal

Quick Facts about Nickel

Co
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +3, +2- common oxidation states in compounds
  • FCC- crystal structure, atomic arrangement in solid form
Cu

Nickel (Ni) is element 28 on the periodic table. Atomic mass of Ni: 58.6930 u. Ni is in period 4, group 10. Melting point of Ni: 1728.00 K.Density of Ni: 8.91 g/cm³.

Why Nickel Matters

The metal in your batteries, coins, and the asteroid that killed the dinosaurs

In Your Home

  • Rechargeable batteries (NiMH, NiCd)
  • Stainless steel appliances
  • Some coins (US nickel is 75% copper)
  • White gold jewelry (gold-nickel alloy)

Industry Uses

SteelStainless steel and specialty alloys
BatteryNiMH batteries in hybrids, NiCd in tools
PlatingElectroplating for corrosion resistance
CatalystsHydrogenation of vegetable oils

In Your Body

✓ Essential for life

Essential in trace amounts for some enzymes. Plants and bacteria need nickel. Uncertain if essential for humans but likely.

Safety: Nickel allergy is common (10-20% of population). Ingested nickel is poorly absorbed. Nickel carbonyl gas is extremely toxic.

Discovery of Nickel

Discovered by Axel Cronstedt in Sweden, 1751

Name origin: German: kupfernickel (false copper).

History & Events

1751
Discovery
Axel Fredrik Cronstedt isolated nickel from 'kupfernickel' ore
1881
Electric Battery
Waldemar Jungner invented nickel-cadmium battery
1980
Dinosaur Extinction Link
Alvarez team found iridium-nickel anomaly, linking asteroid to dinosaur extinction

About Nickel

Malleable ductile silvery metallic transition element. Discovered by A.F. Cronstedt in 1751.

Atomic Properties of Ni

Atomic Number of Ni
28
Atomic Mass of Ni
58.6930 u
Electron Configuration
[Ar] 3d8 4s2
Electronegativity
1.91
Block
d-block
Group
10
Period
4

Physical Properties of Ni

Phase (STP)
solid
Melting Point of Ni
1728.00 K
Boiling Point of Ni
3003.00 K
Density of Ni
8.9080 g/cm3

Thermal Properties

Heat of Fusion
17.61 kJ/mol
Heat of Vaporization
378.60 kJ/mol
Specific Heat
0.44 J/g·K
Molar Heat Capacity
26.07 J/mol·K
Thermal Conductivity
90.90 W/m·K

Atomic Radii

Calculated
135 pm
Covalent
110 pm
Van der Waals
197 pm
Metallic
115 pm

Common Misconceptions

Wrong:Nickels are made mostly of nickel.
Correct:US nickels are 75% copper and only 25% nickel. Canadian nickels are now steel.
Wrong:Nickel allergy comes from nickel in food.
Correct:Nickel allergy is a contact allergy—skin reaction to jewelry, buttons, etc., not food.
Wrong:Nickel is named after its discoverer.
Correct:Nickel comes from German 'kupfernickel' (copper devil)—miners' term for ore that looked like copper but yielded none.

Isotopes of Nickel

Nickel has 5 naturally occurring isotopes, plus 2 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
5828Ni (Ni-58)Nickel-58 isotope57.9353424168.08%
5928Ni (Ni-59)Nickel-59 isotope58.93434620%76,000 yearsEC
6028Ni (Ni-60)Nickel-60 isotope59.9307858826.22%
6128Ni (Ni-61)Nickel-61 isotope60.931055571.140%
6228Ni (Ni-62)Nickel-62 isotope61.928345373.635%
6328Ni (Ni-63)Nickel-63 isotope62.92967290%100.1 yearsβ⁻
6428Ni (Ni-64)Nickel-64 isotope63.927966820.9255%

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Nickel have important real-world applications in science and industry.

Geochronology & Dating

Anomalies in 60Ni abundance caused by decay of now extinct 60Fe have been used to study the early history of our Solar System (see section 4.26.2). 59Ni is a cosmogenic radionuclide with a half-life of 7.6×104 years. Decay of 59Ni has been used to assess the terrestrial age of meteorites and to determine abundances of extraterrestrial dust in ice and sediment [230].

Industrial Applications

63Ni (with a half-life of 99 years) is produced from stable 62Ni and is a beta-emitting radionuclide that serves as an electron source together with 55Fe in electron-capture detectors. Electron-capture detectors are used as thickness gauges or as detectors for organic analytes in gas chromatography (Fig. IUPAC.28.2) [108]. 63Ni is also used to ionize substances in ion mobility spectrometry–the basis of the instrument used in airports to screen passengers for drugs and bombs [231]. 63Ni is also used as a fluorescence-inducing source in elemental analysis by X-ray fluorescence spectroscopy and in miniaturized long-lived nuclear batteries [108]. Until the mid-1980s, nuclear batteries were used in pacemakers, but then they were replaced by long-lasting lithium batteries [232].

Abundance

Earth's Crust
84.0 mg/kg
Seawater
5.60×10-4 mg/L

Uses

Used in electroplating and metal alloys because of its resistance to corrosion. Also in nickel-cadmium batteries; as a catalyst and for coins.

Sources

Chiefly found in pentlandite [(Ni,Fe)9S8] ore. The metal is produced by heating the ore in a blast furnace which replaces the sulfur with oxygen. The oxides are then treated with an acid that reacts with the iron not the nickel.

Geochemistry

Goldschmidt
siderophile
Geochemical Class
first series transition metal

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