Periodic Table

Palladium

Transition Metal

Quick Facts about Palladium

Rh
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +3, +2- common oxidation states in compounds
  • FCC- crystal structure, atomic arrangement in solid form
Ag

Palladium (Pd) is element 46 on the periodic table. Atomic mass of Pd: 106.4200 u. Pd is in period 5, group 10. Melting point of Pd: 1828.05 K.Density of Pd: 12.02 g/cm³.

Why Palladium Matters

Palladium in everyday life and industry

In Your Home

  • Catalytic converters use palladium to reduce harmful emissions
  • Hydrogen storage systems rely on palladium's ability to absorb hydrogen
  • White gold jewelry typically contains palladium

Industry Uses

DentistryDentistry uses palladium alloys for crowns and bridges

In Your Body

✗ Not essential

Palladium has no known biological role. Some palladium compounds can cause allergic reactions. Palladium dental alloys are generally well-tolerated.

Safety: The metal is generally considered non-toxic

Discovery of Palladium

Discovered by William Wollaston in England, 1803

Name origin: Named after the asteroid, Pallas, discovered in 1803.

History & Events

1803
Named after the asteroid Pallas, discovered around the same time
1803
Wollaston discovered it in 1803 while examining platinum ore
1803
Wollaston initially sold palladium anonymously, sparking controversy
1989
Cold fusion claims in 1989 involved palladium electrodes (later debunked)

About Palladium

Soft white ductile transition element. Found with some copper and nickel ores. Does not react with oxygen at normal temperatures. Dissolves slowly in hydrochloric acid. Discovered in 1803 by W.H. Wollaston.

Atomic Properties of Pd

Atomic Number of Pd
46
Atomic Mass of Pd
106.4200 u
Electron Configuration
[Kr] 4d10
Electronegativity
2.20
Block
d-block
Group
10
Period
5

Physical Properties of Pd

Phase (STP)
solid
Melting Point of Pd
1828.05 K
Boiling Point of Pd
3236.00 K
Density of Pd
12.0230 g/cm3

Thermal Properties

Heat of Fusion
17.24 kJ/mol
Heat of Vaporization
372.40 kJ/mol
Specific Heat
0.25 J/g·K
Molar Heat Capacity
25.98 J/mol·K
Thermal Conductivity
71.80 W/m·K

Atomic Radii

Calculated
140 pm
Covalent
120 pm
Van der Waals
210 pm
Metallic
128 pm

Common Misconceptions

Wrong:Platinum is always more expensive than palladium.
Correct:Palladium prices exceeded platinum in 2019-2021 due to gasoline catalytic converter demand. Supply constraints can flip the price relationship.
Wrong:Cold fusion with palladium was proven.
Correct:The 1989 Fleischmann-Pons cold fusion claims using palladium electrodes were never reproducibly verified. It remains one of science's most famous failed claims.
Wrong:White gold is a natural alloy.
Correct:White gold is yellow gold mixed with palladium or nickel to neutralize the color. It's often rhodium-plated for extra whiteness.

Isotopes of Palladium

Palladium has 6 naturally occurring isotopes, plus 3 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
10246Pd (Pd-102)Palladium-102 isotope101.90560221.020%
10346Pd (Pd-103)Palladium-103 isotope102.9060870%16.99 daysEC
10446Pd (Pd-104)Palladium-104 isotope103.904030511.14%
10546Pd (Pd-105)Palladium-105 isotope104.905079622.33%
10646Pd (Pd-106)Palladium-106 isotope105.903480427.33%
10746Pd (Pd-107)Palladium-107 isotope106.9051330%6.5 million yearsβ⁻
10846Pd (Pd-108)Palladium-108 isotope107.903891626.46%
10946Pd (Pd-109)Palladium-109 isotope108.905950%13.7 hoursβ⁻
11046Pd (Pd-110)Palladium-110 isotope109.905172211.72%

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Palladium have important real-world applications in science and industry.

Geochronology & Dating

The isotope-amount ratio n(107Pd)/n(107Ag) is used in geochronology to help date major thermal events in the Solar System. Although 107Ag is naturally occurring, 107Ag is also the daughter product of the beta decay of 107Pd. If both excess 107Ag and 107Pd (with a half-life of 6.5×106 years) are present in a sample of extraterrestrial origin, then the material would have formed sometime after 107Pd decayed. The n(107Pd)/n(107Ag) amount ratio can be measured to help determine when the 107Pd decay process began and how much time has elapsed since the material was formed [344], [345], [346], [347], [348].

Medical Applications

Seeds of the radioactive isotope 103Pd are internally placed in the body to fight prostate and other cancers locally. 103Pd has a half-life of 16.99 days and releases energy at about 80 X-rays and 186 Auger electrons per 100 decays of 103Pd. Therefore, this makes this isotope an ideal candidate for internal radiotherapy for the treatment of cancers [349]. The radioisotope 109Pd (with a half-life of 13.5 h) can be used as a form of cancer therapy. For example, 109Pd-labeled porphyrins or porphyrin-like substances are used as diagnostic and therapeutic techniques to help locate and address areas of tumorous growth. Porphyrins accumulate in tumors of the body and when radiolabeled porphyrins are introduced to the body, the X-rays and energy released can help determine the location and even treat the cancerous tumors [350].

Abundance

Earth's Crust
15.00 μg/kg

Uses

Used as a substitue for silver in dental items and jewelry. The pure metal is used as the delicate mainsprings in analog wristwatches. Also used in surgical instruments and as catalyst .

Sources

Obtained with platinum, nickel, copper and mercury ores.

Geochemistry

Goldschmidt
siderophile
Geochemical Class
noble metal

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