Periodic Table

Thorium

Actinide

Quick Facts about Thorium

Ac
  • solid- state of matter at room temperature
  • Radioactive- no stable isotopes exist
  • +4- common oxidation states in compounds
  • FCC- crystal structure, atomic arrangement in solid form
Pa

Thorium (Th) is element 90 on the periodic table. Atomic mass of Th: 232.0400 u. Th is in period 7. Melting point of Th: 2023.00 K.Density of Th: 11.70 g/cm³.

Why Thorium Matters

Thorium in everyday life and industry

In Your Home

  • High-quality camera lenses used thorium (now discontinued)

Industry Uses

IndustryGas mantles for camping lanterns used thorium (historically)
NuclearThorium reactors are researched as safer nuclear power
IndustryWelding electrodes may contain thorium

In Your Body

✗ Not essential

Thorotrast (thorium dioxide) was once used as X-ray contrast and caused cancers decades later. Lung cancer risk from inhaling thorium dust.

Safety: Thorium is radioactive and accumulates in bones. Less radioactive than uranium but still hazardous.

Discovery of Thorium

Discovered by Jöns Berzelius in Sweden, 1828

Name origin: Named for Thor, Norse god of thunder.

History & Events

1828
Named after Thor, Norse god of thunder
1829
Discovered by Jöns Jacob Berzelius in 1829
1828
Thorium reactors were considered before uranium reactors dominated
1828
India has extensive thorium research programs

About Thorium

Grey radioactive metallic element. Belongs to actinoids. Found in monazite sand in Brazil, India and the US. Thorium-232 has a half-life of 1.39x10^10 years. Can be used as a nuclear fuel for breeder reactors. Thorium-232 captures slow Neutrons and breeds uranium-233. Discovered by Jons J. Berzelius in 1829.

Atomic Properties of Th

Atomic Number of Th
90
Atomic Mass of Th
232.0400 u
Electron Configuration
[Rn] 6d2 7s2
Electronegativity
1.30
Block
f-block
Group
Period
7

Physical Properties of Th

Phase (STP)
solid
Melting Point of Th
2023.00 K
Boiling Point of Th
5061.00 K
Density of Th
11.7000 g/cm3

Thermal Properties

Heat of Fusion
16.11 kJ/mol
Heat of Vaporization
513.70 kJ/mol
Specific Heat
0.12 J/g·K
Molar Heat Capacity
27.32 J/mol·K

Atomic Radii

Calculated
180 pm
Covalent
175 pm
Van der Waals
245 pm

Common Misconceptions

Wrong:Thorium reactors are just theoretical.
Correct:Several thorium reactors have operated, including in the US (1960s) and India. The technology is proven but not commercialized.
Wrong:Thorium is a completely safe replacement for uranium.
Correct:Thorium has advantages (less weapons-usable waste, more abundant) but its own challenges—it needs a neutron source to start and produces U-232 which is highly radioactive.
Wrong:Vintage thorium camera lenses are dangerous to own.
Correct:While mildly radioactive, thorium lenses are safe to handle. The main risk would be grinding the glass and inhaling dust. Many photographers still use them.

Isotopes of Thorium

Thorium has 1 naturally occurring isotope, plus 2 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
23090Th (Th-230)Thorium-230 isotope230.0331341
23190Th (Th-231)Thorium-231 isotope231.03630%25.52 hoursβ⁻
23290Th (Th-232)Thorium-232 isotope232.0380558100.00%

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Thorium have important real-world applications in science and industry.

Geochronology & Dating

The decay of 232Th (with a half-life of 1.40×1010 years) to 208Pb is used to date rocks based on the accumulation of the stable daughter product 208Pb. The half-lives of the isotopes between the parent radionuclide 232Th and stable endpoint 208Pb all have much shorter half-lives than thorium. Therefore, the amount of 208Pb that accumulates in a sample is determined primarily by the amount of 232Th parent radionuclide present when the mineral was formed and the time that has elapsed since the mineral solidified [591]. Another dating method, the 230Th/ 234U method, is based on the hypothesis that the sample contains uranium, but no 230Th at the time of its formation. Then, the age of the specimen is determined mainly by the amount of 230Th in the specimen. Reliable ages with this method range from several thousand to approximately 350 thousand years [292].

Industrial Applications

The most precise time and frequency measurements are performed with optical atomic clocks that use as a frequency standard the optical frequency generated as electrons change energy levels. It has been proposed that a nuclear clock, using a nuclear transition could outperform an electron transition. 229mTh, with a half-life of 13.9 h, has been confirmed as a possible candidate for a nuclear clock [592]. The m in 229mTh indicates a metastable state of the isotope. The further development of a nuclear frequency standard will require more precise determinations of the energy and half-life of the isomer.

Abundance

Earth's Crust
9.6 mg/kg
Seawater
1.00×10-6 mg/L

Uses

Used in making strong alloys. Also in ultraviolet photoelectric cells. It is a common ingredient in high-quality lenses. Bombarded with neutrons make uranium-233, a nuclear fuel.

Sources

Found in various minerals like monazite and thorite.

Geochemistry

Goldschmidt
litophile
Geochemical Class
rare earth & related

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