Periodic Table

Californium

Actinide

Quick Facts about Californium

Bk
  • solid- state of matter at room temperature
  • Radioactive- no stable isotopes exist
  • +3- common oxidation states in compounds
Es

Californium (Cf) is element 98 on the periodic table. Atomic mass of Cf: 251.0000 u. Cf is in period 7. Melting point of Cf: 1173.00 K.Density of Cf: 15.10 g/cm³.

Why Californium Matters

Californium in everyday life and industry

In Your Home

  • Cancer treatment research uses californium

Industry Uses

NuclearNeutron sources for starting nuclear reactors use californium
IndustryOil and coal analysis uses californium neutron activation
IndustryMetal detection and quality control use californium

In Your Body

✗ Not essential

Californium-252 has medical research applications. Neutrons from Cf-252 can treat certain cancers. No biological role.

Safety: Californium is radioactive and toxic

Discovery of Californium

Discovered by G.T.Seaborg, S.G.Tompson, A.Ghiorso, K.Street Jr. in United States, 1950

Name origin: Named after the state and University of California.

History & Events

1950
Named after California and UC Berkeley
1950
Discovered by Seaborg's team in 1950
1950
First produced in microgram quantities
1950
Parallels dysprosium's position in the lanthanides

About Californium

Radioactive metallic transuranic element. Belongs to actinoid series. Cf-251 has a half life of about 700 years. Nine isotopes are known. Cf-252 is an intense Neutron source, which makes it an intense Neutron source and gives it a use in Neutron activation analysis and a possible use as a radiation source in medicine. First produced by Glenn T. Seaborg and associates in 1950.

Atomic Properties of Cf

Atomic Number of Cf
98
Atomic Mass of Cf
251.0000 u
Electron Configuration
[Rn] 5f10 7s2
Electronegativity
1.30
Block
f-block
Group
Period
7

Physical Properties of Cf

Phase (STP)
solid
Melting Point of Cf
1173.00 K
Boiling Point of Cf
1743.00 K
Density of Cf
15.1000 g/cm3

Atomic Radii

Covalent
168 pm
Van der Waals
245 pm

Common Misconceptions

Wrong:Californium is just a laboratory curiosity with no real uses.
Correct:Cf-252 is used industrially for neutron radiography, oil well logging, and starting nuclear reactors.
Wrong:Californium needs external neutron bombardment to produce neutrons.
Correct:Cf-252 spontaneously fissions, emitting neutrons without any external trigger—making it an ideal portable neutron source.
Wrong:Californium is relatively affordable compared to other elements.
Correct:Californium was once the most expensive substance by mass at ~$27 million per gram due to difficult production.

Isotopes of Californium

Californium has 0 naturally occurring isotopes, plus 4 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
24998Cf (Cf-249)Californium-249 isotope249.0748539
25098Cf (Cf-250)Californium-250 isotope250.0764062
25198Cf (Cf-251)Californium-251 isotope251.0795886
25298Cf (Cf-252)Californium-252 isotope252.0816272

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Californium have important real-world applications in science and industry.

Industrial Applications

252Cf is a very active source of neutrons (2.3×106 neutrons per second per microgram) with a half-life of 2.65 years. The energy spectrum of the neutrons is very similar to that of a fission reactor and small amounts of 252Cf provide an ideal portable source for low neutron flux applications [75], [625], [626]. 252Cf is used for PGNAA (prompt gamma neutron activation analysis, a method for detecting many chemical elements in samples simultaneously) in the analysis of coal, cement, minerals, weapon components, and chemical munitions [627]. This method provides a quick and non-destructive elemental analysis of a sample. For example, 252Cf, as the neutron source for PGNAA, is used to detect the presence of antitank mines [625]. Neutron activation analysis (NAA) uses 252Cf as a portable neutron source to bombard a small sample from the area of interest with neutrons and analyze the radioactive emissions from that bombardment to help identify silver or gold ore [75]. 252Cf has been used in neutron moisture gauges to locate water [628]. 252Cf is used in borehole geophysical logging for subsurface PGNAA investigation of waste (Fig. IUPAC.98.1) [629]. Formation fluid identification uses 252Cf as a chemical neutron source for elastic/inelastic neutron backscattering and/or neutron activation methods in well-logging to determine water- and oil-bearing layers and other downhole properties of the well bore [629].

Medical Applications

252Cf is sometimes used in boron neutron capture therapy (BNCT) as a source of neutrons that can be delivered close to the region of a tumor [75], [625], [626]. Brachytherapy can use 252Cf to treat many types of cancer [75], [625], [626].

Uses

It has no significant commercial applications.

Sources

Made by bombarding curium with helium ions.

Geochemistry

Goldschmidt
synthetic

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