Periodic Table

Plutonium

Actinide

Quick Facts about Plutonium

Np
  • solid- state of matter at room temperature
  • Radioactive- no stable isotopes exist
  • +6, +5, +4, +3- common oxidation states in compounds
  • MCL- crystal structure, atomic arrangement in solid form
Am

Plutonium (Pu) is element 94 on the periodic table. Atomic mass of Pu: 244.0000 u. Pu is in period 7. Melting point of Pu: 912.50 K.Density of Pu: 19.85 g/cm³.

Why Plutonium Matters

Plutonium in everyday life and industry

In Your Home

  • Curiosity rover on Mars is powered by plutonium

Industry Uses

Nuclear weaponsNuclear weapons use plutonium as fissile material
SpaceSpace probe power sources use plutonium-238
NuclearNuclear reactors produce plutonium from uranium

In Your Body

✗ Not essential

Accumulates in bones and liver. Microgram quantities can cause cancer.

Safety: Plutonium is extremely toxic, both chemically and radioactively. Inhalation of particles is particularly dangerous.

Discovery of Plutonium

Discovered by G.T.Seaborg, J.W.Kennedy, E.M.McMillan, A.C.Wohl in United States, 1940

Name origin: Named for the planet Pluto.

History & Events

1940
Named after Pluto, continuing the uranium-neptunium pattern
1940
Discovered at Berkeley in 1940 by Seaborg, McMillan, Kennedy, and Wahl
1940
Discovery was kept secret during WWII
1940
Used in the Fat Man bomb dropped on Nagasaki

About Plutonium

Dense silvery radioactive metallic transuranic element, belongs to the actinoids. Pu-244 is the most stable isotope with a half-life of 7.6*10^7 years. Thirteen isotopes are known. Pu-239 is the most important, it undergoes nuclear fission with slow neutrons and is hence important to nuclear weapons and reactors. Plutonium production is monitored down to the gram to prevent military misuse. First produced by Gleen T. Seaborg, Edwin M. McMillan, J.W. Kennedy and A.C. Wahl in 1940.

Atomic Properties of Pu

Atomic Number of Pu
94
Atomic Mass of Pu
244.0000 u
Electron Configuration
[Rn] 5f6 7s2
Electronegativity
1.28
Block
f-block
Group
Period
7

Physical Properties of Pu

Phase (STP)
solid
Melting Point of Pu
912.50 K
Boiling Point of Pu
3505.00 K
Density of Pu
19.8500 g/cm3

Thermal Properties

Heat of Fusion
2.80 kJ/mol
Heat of Vaporization
343.50 kJ/mol

Atomic Radii

Calculated
175 pm
Covalent
172 pm
Van der Waals
243 pm

Common Misconceptions

Wrong:Plutonium is the most toxic substance known.
Correct:Biological toxins like botulinum are far more toxic by mass. Plutonium's danger is primarily from alpha radiation when inhaled or ingested.
Wrong:Any contact with plutonium is immediately fatal.
Correct:Plutonium metal can be briefly handled because alpha radiation doesn't penetrate skin. Inhalation or ingestion is the real danger.
Wrong:Pu-238 used in space probes is weapons-grade material.
Correct:Pu-238 (for RTGs) is a different isotope from weapons-grade Pu-239; it produces heat but cannot sustain a chain reaction.

Isotopes of Plutonium

Plutonium has 0 naturally occurring isotopes, plus 6 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
23894Pu (Pu-238)Plutonium-238 isotope238.0495601
23994Pu (Pu-239)Plutonium-239 isotope239.0521636
24094Pu (Pu-240)Plutonium-240 isotope240.0538138
24194Pu (Pu-241)Plutonium-241 isotope241.0568517
24294Pu (Pu-242)Plutonium-242 isotope242.0587428
24494Pu (Pu-244)Plutonium-244 isotope244.0642053

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Plutonium have important real-world applications in science and industry.

Industrial Applications

238Pu (with a half-life of 87.7 years) is used in radiothermal generators as a heat source to produce electricity. These radiothermal generators are used to power unmanned spacecraft and interplanetary probes that venture too far from the Sun to use solar power, such as the Cassini Orbiter, the Galileo spacecraft, and the Huygens and Galileo probes [75], [606], [607], [608]. 238Pu has been used in the Apollo lunar missions as part of a nuclear battery. The SNAP-27 (systems nuclear auxiliary power) system produced approximately 75 W of electrical power at 30 VDC per unit (Fig. IUPAC.94.1). The energy source was a 2.5-kg rod of 238Pu providing thermal power of approximately 1250 W [609]. 238Pu is used in pacemakers (Fig. IUPAC.94.2). 239Pu (with a half-life of 2.41×104 years) is used in nuclear weapons. 239Pu is easily made in nuclear reactors by bombarding 238U with neutronsvia the reaction 238U (n, γ) 239U and 239U→ 239Pu+β −. The 239Pu made by this reaction can itself be split by neutrons to release energy and is used for energy generation in nuclear reactors [75], [610], [611].

Uses

Used in bombs and reactors. Small quantities are used in thermo-electric generators.

Sources

Found rarely in some uranium ores. Made by bombarding uranium with neutrons.

Geochemistry

Goldschmidt
synthetic

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