Periodic Table

Radium

Alkaline Earth Metal

Quick Facts about Radium

Fr
  • solid- state of matter at room temperature
  • Radioactive- no stable isotopes exist
  • +2- common oxidation states in compounds
Ac

Radium (Ra) is element 88 on the periodic table. Atomic mass of Ra: 226.0000 u. Ra is in period 7, group 2. Melting point of Ra: 973.00 K.Density of Ra: 5.50 g/cm³.

Why Radium Matters

The element that taught us radiation is dangerous

In Your Home

  • Antique luminous watch dials (pre-1970s) may contain radium

Industry Uses

MedicalRa-223 (Xofigo) treats metastatic bone cancer
HistoricalLuminous paint for watch dials (discontinued after Radium Girls tragedy)

In Your Body

✗ Not essential

The 'Radium Girls' suffered bone cancer from painting watch dials. Mimics calcium and accumulates in bones. Causes bone cancer and bone necrosis.

Safety: Radium is highly radioactive and accumulates in bones

Discovery of Radium

Discovered by Pierre and Marie Curie in France, 1898

Name origin: Latin: radius (ray).

History & Events

1898
Named from Latin 'radius' meaning ray
1898
Discovered by Marie and Pierre Curie in 1898
1898
Once thought to be healthful - added to water, toothpaste, even suppositories
1898
The dangers became clear only in the 1920s-30s

About Radium

Radioactive metallic transuranic element, belongs to group 2 of the periodic table. Most stable isotope, Ra-226 has a half-life of 1602 years, which decays into radon. Isolated from pitchblende in 1898 Marie and Pierre Curie.

Atomic Properties of Ra

Atomic Number of Ra
88
Atomic Mass of Ra
226.0000 u
Electron Configuration
[Rn] 7s2
Electronegativity
0.90
Block
s-block
Group
2
Period
7

Physical Properties of Ra

Phase (STP)
solid
Melting Point of Ra
973.00 K
Boiling Point of Ra
2010.00 K
Density of Ra
5.5000 g/cm3

Thermal Properties

Heat of Fusion
9.60 kJ/mol
Heat of Vaporization
113.00 kJ/mol

Atomic Radii

Calculated
215 pm
Covalent
201 pm
Van der Waals
283 pm

Common Misconceptions

Wrong:Radium glows green.
Correct:Pure radium emits a faint blue glow. The green glow in old watch dials came from zinc sulfide phosphors activated by radium's radiation.
Wrong:Radium products were just scams by people who knew better.
Correct:People genuinely believed radium was healthful in the early 1900s. 'Mild radium therapy' was prescribed by doctors until the dangers became clear.
Wrong:Marie Curie died from radium exposure.
Correct:Curie died of aplastic anemia, likely from X-ray exposure during WWI mobile radiography units, not directly from radium research.

Isotopes of Radium

Radium has 0 naturally occurring isotopes, plus 4 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
22388Ra (Ra-223)Radium-223 isotope223.0185023
22488Ra (Ra-224)Radium-224 isotope224.020212
22688Ra (Ra-226)Radium-226 isotope226.0254103
22888Ra (Ra-228)Radium-228 isotope228.0310707

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Radium have important real-world applications in science and industry.

Geochronology & Dating

226Ra and 228Ra can be used for dating materials up to a few thousand years in age because the half-lives of 226Ra and 228Ra are 1600 years and 5.75 years, respectively, even though the long-lived 226Ra is found in nature as a result of its continuous production by the decay of 238U. For example, long-lived 226Ra has been used to date a limestone cave in central Switzerland, corals in the Indian Ocean, and Pleistocene gravel terraces [580]. The activity ratio A(224Ra)/A(223Ra) is a potential age calculator for old lake water because the low 223Ra and 224Ra activities in old lake water are relatively unaffected by mixing [579].

Medical Applications

226Ra is used in brachytherapy (Fig. IUPAC.88.1), which is a method of localized treatment of various types of cancer. A sealed implant (such as a rod, seed, or needle) containing the radioactive isotope 226Ra is inserted into or near a patient’s tumor to apply a high dose of radiation to the tumor. The sealed implant is inserted by a physician or by an automated device (called a remote afterloader), and it is removed from the patient once the tumor is destroyed [75], [581].

Abundance

Earth's Crust
9.00×10-7 mg/kg
Seawater
8.90×10-11 mg/L

Uses

Used in treating cancer because of the gamma rays it gives off.

Sources

Found in uranium ores at 1 part per 3 million parts uranium.

Geochemistry

Goldschmidt
litophile
Geochemical Class
U/Th decay series

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