Periodic Table

Beryllium

Alkaline Earth Metal

Quick Facts about Beryllium

Li
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +2- common oxidation states in compounds
  • HEX- crystal structure, atomic arrangement in solid form
B

Beryllium (Be) is element 4 on the periodic table. Atomic mass of Be: 9.0122 u. Be is in period 2, group 2. Melting point of Be: 1560.00 K.Density of Be: 1.85 g/cm³.

Why Beryllium Matters

Beryllium in everyday life and industry

In Your Home

  • High-end audio speaker domes use beryllium for superior sound quality

Industry Uses

Aerospace componentsAerospace components use beryllium for its light weight and stiffness
SpaceThe James Webb Space Telescope mirrors are made of beryllium
Medical imagingX-ray machine windows use beryllium (transparent to X-rays)

In Your Body

✗ Not essential

The body has no use for beryllium Only about 1-15% of exposed people develop beryllium sensitivity

Safety: Beryllium is highly toxic - one of the most poisonous elements Beryllium exposure causes chronic beryllium disease (CBD) in lungs

Discovery of Beryllium

Discovered by Fredrich Wöhler, A.A.Bussy in Germany/France, 1798

Name origin: Greek: beryllos, "beryl" (a mineral).

History & Events

1798
Name from Greek 'beryllos' for the beryl gemstone
1798
Emeralds and aquamarines are beryllium-containing beryls
1798
Originally called 'glucinium' from Greek 'glykys' (sweet) for its sweet-tasting compounds
1798
The sweet taste is ironic given its extreme toxicity

About Beryllium

Grey metallic element of group 2 of the periodic table. Is toxic and can cause severe lung diseases and dermatitis. Shows high covalent character. It was isolated independently by F. Wohler and A.A. Bussy in 1828.

Atomic Properties of Be

Atomic Number of Be
4
Atomic Mass of Be
9.0122 u
Electron Configuration
[He] 2s2
Electronegativity
1.57
Block
s-block
Group
2
Period
2

Physical Properties of Be

Phase (STP)
solid
Melting Point of Be
1560.00 K
Boiling Point of Be
2742.00 K
Density of Be
1.8500 g/cm3

Thermal Properties

Heat of Fusion
12.21 kJ/mol
Heat of Vaporization
309.00 kJ/mol
Specific Heat
1.82 J/g·K
Molar Heat Capacity
16.44 J/mol·K
Thermal Conductivity
201.00 W/m·K

Atomic Radii

Calculated
105 pm
Covalent
102 pm
Van der Waals
153 pm
Metallic
89 pm

Common Misconceptions

Wrong:Beryllium disease is an allergy.
Correct:It's an immune system granulomatous condition
Wrong:Solid beryllium is dangerous to touch.
Correct:Only dust and fumes are hazardous
Wrong:Beryllium is rare.
Correct:It's just difficult and dangerous to process

Isotopes of Beryllium

Beryllium has 1 naturally occurring isotope, plus 2 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
74Be (Be-7)Beryllium-7 isotope7.016928720%53.2 daysEC
94Be (Be-9)Beryllium-9 isotope9.012183065100.00%
104Be (Be-10)Beryllium-10 isotope10.01353470%1.39 million yearsβ⁻

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Beryllium have important real-world applications in science and industry.

Geochronology & Dating

Cosmogenic 10Be and 7Be isotopes are produced in the atmosphere, largely by cosmic-ray spallation of nitrogen and oxygen. Because of its relatively short half-life (7Be, half-life t1/2=53 d, compared to that of 10Be, half-life t1/2=1.39×106 a, where the unit symbol “d” stands for day and “a” stands for year), measurements of cosmogenic 7Be, and especially the isotope-amount ratio n(7Be)/n(10Be), have been used to study rates of atmospheric circulation, mixing, formation of aerosols (fine solids or liquids suspended in a gas; e.g. smoke and mist are aerosols), and particle deposition [44]. Cosmogenic atmospheric beryllium isotopes (7Be and 10Be) are deposited on the Earth’s surface, where they accumulate in soils, sediments, and snow while decaying away. Measurements of cosmogenic beryllium isotopes in such deposits are used to explore rates of soil formation, erosion, sedimentation, and snow accumulation on time scales ranging from months (7Be) to millions of years (10Be) [45], [46]. The minerals in rocks at the Earth’s surface interact with cosmic rays and form substantial quantities of 10Be and 7Be, thus providing a tool to determine the ages of geologic processes. In some situations, it is possible to estimate “exposure ages” for rocks in eroding terrains [47], [48], [49]. By comparing measured 10Be concentrations with estimated rates of in situ cosmogenic 10Be production, the rate of rock erosion and formation of canyons and other geologic features can be determined (Fig. IUPAC.4.1). Anthropogenic 10Be was produced by nuclear bomb explosions largely through the reaction of fast neutrons (neutrons produced by nuclear fission having high kinetic energy) with 13C via the 13C (n, alpha) 10Be reaction in atmospheric CO2. Although the quantity of 10Be produced in this way is small, its presence above natural background concentrations in some environmental samples can potentially provide information about bomb-related processes and contamination [50].

Abundance

Earth's Crust
2.8 mg/kg
Seawater
5.60×10-6 mg/L

Uses

Its ability to absorb large amounts of heat makes it useful in spacecraft, missiles, aircraft, etc. Emeralds are beryl crystals with chromium traces giving them their green color.

Sources

Found mostly in minerals like beryl [AlBe3(Si6O18)] and chrysoberyl (Al2BeO4). Pure beryllium is obtained by chemically reducing beryl mineral. Also by electrolysis of beryllium chloride.

Geochemistry

Goldschmidt
litophile
Geochemical Class
alkaline earth metal

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