Periodic Table

Francium

Alkali Metal

Quick Facts about Francium

Rn
  • solid- state of matter at room temperature
  • Radioactive- no stable isotopes exist
  • +1- common oxidation states in compounds
  • BCC- crystal structure, atomic arrangement in solid form
Ra

Francium (Fr) is element 87 on the periodic table. Atomic mass of Fr: 223.0000 u. Fr is in period 7, group 1. Melting point of Fr: 300.00 K.Density of Fr: 1.87 g/cm³.

Why Francium Matters

The most unstable naturally occurring element

Industry Uses

ResearchAtomic physics research on heavy alkali metals

In Your Body

✗ Not essential

Francium would behave like other alkali metals biologically. Would likely concentrate in bone like cesium if it lasted longer. No practical biological studies are possible.

Safety: Too radioactive and short-lived to exist in living systems

Discovery of Francium

Discovered by Marguerite Derey in France, 1939

Name origin: Named for France, the nation of its discovery.

History & Events

1939
Named after France, homeland of discoverer Marguerite Perey
1939
Last naturally occurring element to be discovered (1939)
1939
Perey was Marie Curie's assistant
1939
Most unstable of naturally occurring elements

About Francium

Radioactive element, belongs to group 1 of the periodic table. Found in uranium and thorium ores. The 22 known isotopes are all radioactive, with the most stable being Fr-223. Its existence was confirmed in 1939 by Marguerite Perey.

Atomic Properties of Fr

Atomic Number of Fr
87
Atomic Mass of Fr
223.0000 u
Electron Configuration
[Rn] 7s1
Electronegativity
0.79
Block
s-block
Group
1
Period
7

Physical Properties of Fr

Phase (STP)
solid
Melting Point of Fr
300.00 K
Boiling Point of Fr
950.00 K
Density of Fr
1.8700 g/cm3

Thermal Properties

Heat of Fusion
15.00 kJ/mol

Atomic Radii

Covalent
223 pm
Van der Waals
348 pm

Common Misconceptions

Wrong:Francium is the rarest element.
Correct:Astatine is rarer. Only about 20-30 grams of francium exist on Earth at any time.
Wrong:We know what francium looks like.
Correct:No one has ever seen bulk francium. Samples are too small and decay too fast (t1/2=22 min) to observe.
Wrong:Francium would explode dramatically in water like other alkali metals.
Correct:While francium is the most reactive alkali metal, there's never enough of it to see an explosion—at most a few thousand atoms at once.

Isotopes of Francium

Francium has 0 naturally occurring isotopes, plus 1 notable radioactive isotope.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
22387Fr (Fr-223)Francium-223 isotope223.019736

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Uses

Since its isotopes have such short half-lives there are no commercially significant compounds of francium.

Sources

Formed by decay of actinium. Chemical properties similar to cesium. Decays to radium or astatine.

Geochemistry

Goldschmidt
synthetic
Geochemical Class
U/Th decay series

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