Periodic Table

Promethium

Lanthanide

Quick Facts about Promethium

Nd
  • solid- state of matter at room temperature
  • Radioactive- no stable isotopes exist
  • +3- common oxidation states in compounds
Sm

Promethium (Pm) is element 61 on the periodic table. Atomic mass of Pm: 145.0000 u. Pm is in period 6. Melting point of Pm: 1315.00 K.Density of Pm: 7.26 g/cm³.

Why Promethium Matters

Promethium in everyday life and industry

In Your Home

  • Historical: luminous watch dials before safety concerns arose
  • Historical: pacemaker batteries (replaced by lithium)

Industry Uses

ManufacturingPm-147 thickness gauges measure paper, plastic, and metal sheets without contact
AerospaceBetavoltaic batteries for long-duration space missions (research stage)

In Your Body

✗ Not essential

No naturally occurring promethium exists to affect biology. Half-life is too short for significant environmental accumulation.

Safety: Radioactive hazard. Beta radiation from Pm-147 is stopped by skin but can damage bone marrow if ingested or inhaled.

Discovery of Promethium

Discovered by J.A. Marinsky, L.E. Glendenin, C.D. Coryell in United States, 1945

Name origin: Named for the Greek god, Prometheus.

History & Events

1945
Named after Prometheus, who stole fire from the gods
1945
Only lanthanide with no stable isotopes
1945
Definitively identified in 1945 from nuclear reactor products
1945
Last lanthanide to be discovered

About Promethium

The only lanthanide with no stable isotopes. Pm-145 is longest-lived (t1/2 17.7 years). Trace amounts occur naturally from spontaneous fission of uranium. Pm-147 (t1/2 2.62 years) is the main commercial isotope—a pure beta emitter ideal for thickness gauges and betavoltaic batteries. Discovered 1945 by Marinsky, Glendenin, and Coryell in fission products at Oak Ridge.

Atomic Properties of Pm

Atomic Number of Pm
61
Atomic Mass of Pm
145.0000 u
Electron Configuration
[Xe] 4f5 6s2
Electronegativity
1.13
Block
f-block
Group
Period
6

Physical Properties of Pm

Phase (STP)
solid
Melting Point of Pm
1315.00 K
Boiling Point of Pm
3273.00 K
Density of Pm
7.2600 g/cm3

Thermal Properties

Thermal Conductivity
17.90 W/m·K

Atomic Radii

Calculated
185 pm
Covalent
173 pm
Van der Waals
238 pm

Common Misconceptions

Wrong:Promethium is entirely artificial with zero natural occurrence.
Correct:Trace amounts (~570 g total in Earth's crust) form continuously from spontaneous fission of U-238. It's vanishingly rare, but not zero.
Wrong:Promethium batteries are dangerous to carry.
Correct:Pm-147 is a pure beta emitter—the radiation can't penetrate skin or a thin metal case. It's safe externally, unlike gamma sources.
Wrong:Promethium was the last element discovered.
Correct:It was the last lanthanide discovered (1945), but many elements came after—all transactinides and several actinides.

Isotopes of Promethium

Promethium has 0 naturally occurring isotopes, plus 2 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
14561Pm (Pm-145)Promethium-145 isotope144.912755917.7 yearsEC, α
14761Pm (Pm-147)Promethium-147 isotope146.9151452.62 yearsβ⁻

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Promethium have important real-world applications in science and industry.

Industrial Applications

The beta-particle-emitting isotope 147Pm (with a half-life of 2.68 years) is used in the nuclear fuel industry to measure the thickness of the inner surface layer of graphite in the cladding tube where the nuclear fuel rod is placed in a nuclear fuel reactor (Fig. IUPAC.61.1). The graphite serves as a protective layer against mechanical contact between the nuclear fuel rod and the Zircaloy cladding (fuel-rod holding tube) and as a diffusion barrier against fission products. By placing a layer of 147Pm along the inner surface of the cladding before the graphite, the long half-life of 147Pm and constant beta-particle emission provide a reliable and simple technique to measure the thickness of the graphite along the inner surface of the tube (called the beta-ray backscatter technique) [432], [433], [434]. The beta decay property of 147Pm makes this radioisotope an ideal candidate for nuclear batteries (beta voltaics). Long-lived power supplies for remote and sometimes hostile environmental conditions are needed for space and sea missions, and nuclear batteries can uniquely serve this role. A nuclear battery using beta voltaics can have an energy density (quantity of energy per unit mass) near a thousand watt-h per kilogram with 21 percent efficiency, which is much greater than the best chemical batteries [435].

Uses

It has been used as a source of radioactivity for thickness-measuring gages.

Sources

Does not occur naturally. Found among fission products of uranium, thorium, and plutonium.

Geochemistry

Goldschmidt
litophile
Geochemical Class
rare earth & related

Test Your Knowledge

Loading quiz...