Periodic Table

Bismuth

Post Transition Metal

Quick Facts about Bismuth

Pb
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +5, +3- common oxidation states in compounds
  • RHL- crystal structure, atomic arrangement in solid form
Po

Bismuth (Bi) is element 83 on the periodic table. Atomic mass of Bi: 208.9800 u. Bi is in period 6, group 15. Melting point of Bi: 544.70 K.Density of Bi: 9.78 g/cm³.

Why Bismuth Matters

Bismuth in everyday life and industry

In Your Home

  • Pepto-Bismol contains bismuth subsalicylate
  • Cosmetics like lipstick contain bismuth oxychloride for shimmer
  • Lead-free solder and shot use bismuth as a replacement

Industry Uses

MetallurgyLow-melting-point alloys for fire sprinklers contain bismuth

In Your Body

✗ Not essential

Bismuth compounds treat stomach ulcers and diarrhea. The 'bismuth tongue' (dark tongue) from Pepto-Bismol is harmless. Bismuth has been used medicinally for over 200 years.

Safety: Bismuth is remarkably non-toxic for a heavy metal, the least toxic of the heavy metals.

Discovery of Bismuth

Discovered by Known to the ancients.,

Name origin: German: bisemutum, (white mass), Now spelled wismut.

History & Events

1753
Name origin uncertain - possibly Arabic or German
1753
Often confused with lead and tin historically
1753
Claude François Geoffroy first showed it was distinct in 1753
2003
Once thought to be the heaviest stable element (until 2003 discovery of slight radioactivity)

About Bismuth

White crystalline metal with a pink tinge, belongs to group 15. Most diamagnetic of all metals and has one of the lowest thermal conductivities among the metals. Lead-free bismuth compounds are used in cosmetics and medical procedures. Burns in the air and produces a blue flame. In 1753, Claude Francois Geoffroy first demonstrated that it was different from lead.

Atomic Properties of Bi

Atomic Number of Bi
83
Atomic Mass of Bi
208.9800 u
Electron Configuration
[Xe] 4f14 5d10 6s2 6p3
Electronegativity
2.02
Block
p-block
Group
15
Period
6

Physical Properties of Bi

Phase (STP)
solid
Melting Point of Bi
544.70 K
Boiling Point of Bi
1837.00 K
Density of Bi
9.7800 g/cm3

Thermal Properties

Heat of Fusion
11.00 kJ/mol
Heat of Vaporization
172.00 kJ/mol
Specific Heat
0.12 J/g·K
Molar Heat Capacity
25.52 J/mol·K
Thermal Conductivity
7.90 W/m·K

Atomic Radii

Calculated
160 pm
Covalent
151 pm
Van der Waals
207 pm
Metallic
151 pm

Common Misconceptions

Wrong:Bismuth is the heaviest stable element.
Correct:In 2003, scientists discovered Bi-209 is radioactive with a half-life of 2×10⁠19 years, a billion times the age of the universe. Lead-208 is now the heaviest stable nuclide.
Wrong:Pepto-Bismol's pink color comes from bismuth.
Correct:Bismuth subsalicylate (the active ingredient) is actually white. The iconic pink color is from added dye, originally chosen to distinguish it from other medicines.
Wrong:The rainbow bismuth crystals you see online are natural.
Correct:Those stunning iridescent hopper crystals are lab-grown. Bismuth expands when it solidifies, creating step-like formations. The rainbow colors are from a thin oxide layer.

Isotopes of Bismuth

Bismuth has 0 naturally occurring isotopes, plus 3 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
20983Bi (Bi-209)Bismuth-209 isotope208.9803991100.00%2.01×10¹⁹ yearsα
21283Bi (Bi-212)Bismuth-212 isotope211.9912860%60.55 minutesβ⁻, α
21383Bi (Bi-213)Bismuth-213 isotope212.9943850%45.59 minutesβ⁻, α

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Selected uses of notable Bismuth isotopes.

Bi-209

Its extraordinarily long alpha-decay half-life ended bismuth's former classification as a stable element

Bi-212

Targeted alpha therapy; part of thorium decay chain

Bi-213

Targeted alpha therapy for cancer; highly cytotoxic to tumor cells

Applications reference: IUPAC Isotopes Matter and NIH PubChem.

Abundance

Earth's Crust
8.50 μg/kg
Seawater
2.00×10-5 mg/L

Uses

Main use is in pharmaceuticals and low melting point alloys used as fuses.

Occurrence and Production

Found free in nature and in minerals like bismuthinite (Bi⁠2S⁠3) and bismite (Bi⁠2O⁠3). Byproduct of copper, lead, and tin refining.

Geochemistry

Goldschmidt
chalcophile

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