Periodic Table

Xenon

Noble Gas

Quick Facts about Xenon

I
  • gas- state of matter at room temperature
  • Stable- has at least one stable isotope
  • 0- common oxidation states in compounds
  • FCC- crystal structure, atomic arrangement in solid form
Cs

Xenon (Xe) is element 54 on the periodic table. Atomic mass of Xe: 131.2900 u. Xe is in period 5, group 18. Melting point of Xe: 161.40 K.Density of Xe: 0.01 g/cm³.

Why Xenon Matters

The anesthetic gas that also powers spacecraft

In Your Home

  • Car headlights (HID/Xenon lights)
  • Camera flash units
  • Plasma TVs (older models)
  • Some medical imaging equipment

Industry Uses

AutomotiveHigh-intensity discharge (HID) headlights
MedicalGeneral anesthetic and medical imaging contrast
AerospaceIon propulsion for spacecraft (Dawn, Starlink satellites)
ResearchDark matter detection experiments

In Your Body

✗ Not essential

No biological role, but has medical uses. Acts as an anesthetic with neuroprotective properties. Being studied for brain injury treatment.

Safety: Non-toxic and non-flammable. At high pressures, acts as an anesthetic. Considered one of the safest anesthetics.

Discovery of Xenon

Discovered by Sir William Ramsay; M. W. Travers in England, 1898

Name origin: Greek: xenos (strange).

History & Events

1898
Discovery
William Ramsay and Morris Travers discovered xenon as a trace component of liquid air
1962
First Noble Gas Compound
Neil Bartlett created xenon hexafluoroplatinate, proving noble gases can form compounds
1998
Ion Propulsion
Deep Space 1 became first spacecraft to use xenon ion propulsion as primary engine

About Xenon

Colorless, odorless gas belonging to group 18 on the periodic table (the noble gases.) Nine natural isotopes and seven radioactive isotopes are known. Xenon was part of the first noble-gas compound synthesized. Several others involving Xenon have been found since then. Xenon was discovered by Ramsey and Travers in 1898.

Atomic Properties of Xe

Atomic Number of Xe
54
Atomic Mass of Xe
131.2900 u
Electron Configuration
[Kr] 4d10 5s2 5p6
Electronegativity
2.60
Block
p-block
Group
18
Period
5

Physical Properties of Xe

Phase (STP)
gas
Melting Point of Xe
161.40 K
Boiling Point of Xe
165.05 K
Density of Xe
0.0059 g/cm3

Thermal Properties

Heat of Vaporization
12.65 kJ/mol
Specific Heat
0.16 J/g·K
Molar Heat Capacity
20.79 J/mol·K
Thermal Conductivity
0.01 W/m·K

Atomic Radii

Covalent
131 pm
Van der Waals
216 pm

Common Misconceptions

Wrong:Noble gases can never form compounds.
Correct:Xenon forms many compounds! XeF2, XeF4, XeO3 and others are well-known.
Wrong:Xenon headlights contain pure xenon.
Correct:HID 'xenon' lights use xenon only for startup. Once running, they use metal halide vapor.
Wrong:Xenon is too rare to be useful.
Correct:While expensive, xenon is extracted from air and has critical uses in medicine, space, and lighting.

Isotopes of Xenon

Xenon has 9 naturally occurring isotopes, plus 2 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
12454Xe (Xe-124)Xenon-124 isotope123.9058920.0952%
12654Xe (Xe-126)Xenon-126 isotope125.90429830.0890%
12754Xe (Xe-127)Xenon-127 isotope126.9051840%36.345 daysEC
12854Xe (Xe-128)Xenon-128 isotope127.9035311.910%
12954Xe (Xe-129)Xenon-129 isotope128.904780926.40%
13054Xe (Xe-130)Xenon-130 isotope129.90350934.071%
13154Xe (Xe-131)Xenon-131 isotope130.905084121.23%
13254Xe (Xe-132)Xenon-132 isotope131.904155126.91%
13354Xe (Xe-133)Xenon-133 isotope132.90591080%5.2475 daysβ⁻
13454Xe (Xe-134)Xenon-134 isotope133.905394710.44%
13654Xe (Xe-136)Xenon-136 isotope135.90721458.857%

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Xenon have important real-world applications in science and industry.

Geochronology & Dating

The stable isotopes of xenon hold many clues about the formation of the elements, solar-system history, and Earth processes [29], [101]. For example, 129Xe has been used as a detector of “extinct” radionuclides. Some 129Xe is radiogenic as a result of being produced by the radioactive decay of 129I (half-life of 1.7×107 years). Because the half-life of 129I is much smaller than the age of the Earth, primordial 129I (i.e. that which was present at the beginning of Earth’s history) is essentially gone after it decayed to 129Xe over geologic time. This means that radiogenic 129Xe could be a marker of the former existence of the “extinct” isotope 129I. Because primordial 129I was produced largely in supernovae, detection of radiogenic 129Xe in meteorites and terrestrial samples also implies that the time elapsed between 129I supernova nucleosynthesis and planetary condensation was short compared to the subsequent history of the Solar System. The many isotopes and reaction mechanisms of xenon have contributed numerous insights into Earth processes through the study of “xenology” (xenon isotopic variations used as geodynamic tracers to study the dynamics of the Earth) [397].

Medical Applications

Xenon isotopes are used in numerous ways to investigate the movement of inhaled gases in lungs and other parts of the body. If radioactive isotopes of xenon [ 127Xe (with a half-life of 0.1 year), 133Xe, and hyperpolarized (having non-equilibrium alignment of nuclear spins, suitable for magnetic resonance) 129Xe] are inhaled, they can be tracked throughout the body by externally monitoring their decay products using magnetic resonance microscopy [high resolution magnetic resonance imaging (MRI) at microscopic (nanometer) levels] (Fig. IUPAC.54.2). This imaging technique is used to assess how well oxygen is taken up and transported by the blood [398].

Abundance

Earth's Crust
3.00×10-5 mg/kg
Seawater
5.00×10-5 mg/L

Uses

Used for filling flash lamps and other powerful lamps. Electrical excitation of xenon produces a burst of brilliant whtie light. Also used in bubble chambers and modern nuclear power reactors.

Sources

Obtain from the small quantities in liquid air.

Geochemistry

Goldschmidt
atmophile
Geochemical Class
volatile

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