Periodic Table

Krypton

Noble Gas

Quick Facts about Krypton

Br
  • gas- state of matter at room temperature
  • Stable- has at least one stable isotope
  • 0- common oxidation states in compounds
  • FCC- crystal structure, atomic arrangement in solid form
Rb

Krypton (Kr) is element 36 on the periodic table. Atomic mass of Kr: 83.7980 u. Kr is in period 4, group 18. Melting point of Kr: 115.78 K.Density of Kr: 0.00 g/cm³.

Why Krypton Matters

Not Superman's weakness, but it does define the meter

In Your Home

  • Energy-efficient windows (better insulator than argon)
  • Camera flash bulbs
  • Some fluorescent lights
  • Airport runway lights

Industry Uses

LightingHigh-intensity discharge lamps and flash photography
WindowsPremium insulating gas (better than argon but more expensive)
LasersKrypton-fluoride (KrF) excimer lasers for deep-ultraviolet photolithography in chip manufacturing
StandardsFormerly used to define the meter (1960-1983)

In Your Body

✗ Not essential

No biological function. Completely inert. Present in trace amounts in air (1 ppm).

Safety: Non-toxic. Can act as an anesthetic at high pressures (like xenon). May cause asphyxiation.

Discovery of Krypton

Discovered by Sir William Ramsay, M.W. Travers in Great Britain, 1898

Name origin: Greek: kryptos (hidden).

History & Events

1898
Discovery
William Ramsay and Morris Travers discovered krypton while studying liquid air
1960
Defined the Meter
The meter was redefined as 1,650,763.73 wavelengths of krypton-86 orange-red light
1983
Speed of Light Standard
The meter definition changed to light-speed based, ending krypton's role

About Krypton

Colorless gaseous element, belongs to the noble gases. Occurs in the air, 0.0001% by volume. It can be extracted from liquid air by fractional distillation. Generally not isolated, but used with other inert gases in fluorescent lamps. Five natural isotopes, and five radioactive isotopes. Kr-85, the most stable radioactive isotope, has a half-life of 10.76 years and is produced in fission reactors. Practically inert, though known to form compounds with Fluorine.

Atomic Properties of Kr

Atomic Number of Kr
36
Atomic Mass of Kr
83.7980 u
Electron Configuration
[Ar] 3d10 4s2 4p6
Electronegativity
3.00
Block
p-block
Group
18
Period
4

Physical Properties of Kr

Phase (STP)
gas
Melting Point of Kr
115.78 K
Boiling Point of Kr
119.93 K
Density of Kr
0.0037 g/cm3

Thermal Properties

Heat of Vaporization
9.05 kJ/mol
Specific Heat
0.25 J/g·K
Molar Heat Capacity
20.79 J/mol·K
Thermal Conductivity
0.01 W/m·K

Atomic Radii

Covalent
117 pm
Van der Waals
202 pm

Common Misconceptions

Wrong:Kryptonite from Superman is related to krypton.
Correct:Superman's kryptonite is fictional. Real krypton is a harmless noble gas named from Greek 'kryptos' (hidden).
Wrong:Krypton is extremely rare.
Correct:While rare on Earth (1 ppm in air), krypton is produced industrially from liquid air distillation.
Wrong:Krypton is radioactive.
Correct:Natural krypton is stable. Only certain artificial isotopes (like Kr-85 from nuclear reactors) are radioactive.

Isotopes of Krypton

Krypton has 6 naturally occurring isotopes, plus 2 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
7836Kr (Kr-78)Krypton-78 isotope77.920364940.3550%
8036Kr (Kr-80)Krypton-80 isotope79.916378082.286%
8136Kr (Kr-81)Krypton-81 isotope80.91659120%229,000 yearsEC
8236Kr (Kr-82)Krypton-82 isotope81.9134827311.59%
8336Kr (Kr-83)Krypton-83 isotope82.9141271611.50%
8436Kr (Kr-84)Krypton-84 isotope83.9114977356.99%
8536Kr (Kr-85)Krypton-85 isotope84.91252730%10.76 yearsβ⁻
8636Kr (Kr-86)Krypton-86 isotope85.9106106317.28%

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Selected uses of notable Krypton isotopes.

Kr-81

Groundwater dating; polar ice core dating

Kr-85

Atmospheric tracer; nuclear reprocessing monitor; leak detection

Applications reference: IUPAC Isotopes Matter and NIH PubChem.

Abundance

Earth's Crust
1.00×10-4 mg/kg
Seawater
2.10×10-4 mg/L

Uses

Used in lighting products. Some is used as inert filler-gas in incandescent bulbs. Some is mixed with argon in fluorescent lamps. The most important use is in flashing stroboscopic lamps that outline airport runways.

Occurrence and Production

Forms 1 millionth of the atmosphere. Obtained from production of liquid air.

Geochemistry

Goldschmidt
atmophile
Geochemical Class
volatile

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