Periodic Table

Iodine

Halogen

Quick Facts about Iodine

Te
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +7, +5, +1, -1- common oxidation states in compounds
  • ORC- crystal structure, atomic arrangement in solid form
Xe

Iodine (I) is element 53 on the periodic table. Atomic mass of I: 126.9000 u. I is in period 5, group 17. Melting point of I: 386.85 K.Density of I: 4.93 g/cm³.

Why Iodine Matters

The element that keeps your thyroid healthy and wounds clean

In Your Home

  • Iodized salt (prevents goiter)
  • Antiseptic solutions (iodine/Betadine)
  • Contrast dye for medical imaging
  • Water purification tablets

Industry Uses

MedicalContrast agents for X-rays and CT scans
NutritionIodized salt prevents iodine deficiency worldwide
NuclearRadioactive I-131 treats thyroid cancer
PhotographySilver iodide in traditional film (historical)

In Your Body

✓ Essential for life

Essential for thyroid hormones (T3, T4) that regulate metabolism. Deficiency causes goiter and developmental problems. Your body contains about 20mg.

Safety: Excess iodine can cause thyroid problems. Concentrated iodine solutions irritate skin. Radioactive I-131 requires careful handling.

Discovery of Iodine

Discovered by Bernard Courtois in France, 1811

Name origin: Greek: iôeides (violet colored).

History & Events

1811
Discovery
Bernard Courtois discovered iodine in seaweed ash while making saltpeter for Napoleon's army
1924
Iodized Salt
US introduced iodized salt, dramatically reducing goiter rates
1946
Medical Isotope
I-131 first used to treat thyroid cancer, pioneering nuclear medicine

About Iodine

Dark violet nonmetallic element, belongs to group 17 of the periodic table. Insoluble in water. Required as a trace element for living organisms. One stable isotope, I-127 exists, in addition to fourteen radioactive isotopes. Chemically the least reactive of the halogens, and the most electropositive metallic halogen. Discovered in 1812 by Courtois.

Atomic Properties of I

Atomic Number of I
53
Atomic Mass of I
126.9000 u
Electron Configuration
[Kr] 4d10 5s2 5p5
Electronegativity
2.66
Block
p-block
Group
17
Period
5

Physical Properties of I

Phase (STP)
solid
Melting Point of I
386.85 K
Boiling Point of I
457.40 K
Density of I
4.9330 g/cm3

Thermal Properties

Heat of Fusion
15.52 kJ/mol
Heat of Vaporization
41.95 kJ/mol
Specific Heat
0.21 J/g·K
Molar Heat Capacity
54.43 J/mol·K

Atomic Radii

Calculated
140 pm
Covalent
133 pm
Van der Waals
198 pm

Common Misconceptions

Wrong:All salt contains iodine.
Correct:Only iodized salt has added iodine. Sea salt, kosher salt, and specialty salts usually don't.
Wrong:Iodine is only for wounds.
Correct:Dietary iodine is essential! Iodine deficiency is the world's leading cause of preventable intellectual disability.
Wrong:You can get enough iodine from seafood.
Correct:Unless you eat seafood very regularly, you may need iodized salt or other sources.

Isotopes of Iodine

Iodine has 1 naturally occurring isotope, plus 5 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
12353I (I-123)Iodine-123 isotope122.9055890%13.2 hoursEC
12453I (I-124)Iodine-124 isotope123.90620990%4.18 daysEC, β⁺
12553I (I-125)Iodine-125 isotope124.90463020%59.4 daysEC
12753I (I-127)Iodine-127 isotope126.9044719100.00%
12953I (I-129)Iodine-129 isotope128.9049880%15.7 million yearsβ⁻
13153I (I-131)Iodine-131 isotope130.90612460%8.02 daysβ⁻

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Isotopes of Iodine have important real-world applications in science and industry.

Geochronology & Dating

Natural cosmogenic 129I enters groundwater and other terrestrial environments from the atmosphere and then decays to 129Xe. The isotope-amount ratio n(129I)/n(127I) can be used as a clock to estimate time since cosmogenic 129I entered the system. The amount of product 129Xe in such cases is too small to measure; however, excess quantities of 129Xe can be found in meteorites and other very old samples that contained extinct primordial 129I. Younger water bodies also can be differentiated from older water bodies by determining the amount of anthropogenic 129I released since the 1960s from sources such as nuclear bomb tests [393], [394].

Medical Applications

125I, which has a half-life of about 59 days, is used encapsulated in radiotherapy to target and treat sites of cancerous tumors [395]. 120gI (with a half-life of 1.36 h), where the “g” indicates ground state, and 124I (with a half-life of 100 h) are radioactive isotopes that emit positrons and they are used in quantitative, diagnostic imaging of the body using positron emission tomography (PET) [383], [384], [385], [387], [388], [389]. 123I and 131I (with half-lives of 0.55 day and 8 days, respectively) are used with single-photon emission computed spectroscopy (SPECT) for basic three-dimensional imaging [386], [395]. Radioactive iodine isotopes are produced from radioactive tellurium isotope.

Abundance

Earth's Crust
450.00 μg/kg
Seawater
60.00 μg/kg

Uses

Required in small amounts by humans. Once used as an antiseptic, but no longer due to its poisonous nature.

Sources

Occurs on land and in the sea in sodium and potassium compounds.

Geochemistry

Goldschmidt
litophile
Geochemical Class
semi-volatile

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