Periodic Table

Iodine

Halogen

Quick Facts about Iodine

Te
  • solid- state of matter at room temperature
  • Stable- has at least one stable isotope
  • +7, +5, +1, -1- common oxidation states in compounds
  • ORC- crystal structure, atomic arrangement in solid form
Xe

Iodine (I) is element 53 on the periodic table. Atomic mass of I: 126.9000 u. I is in period 5, group 17. Melting point of I: 386.85 K.Density of I: 4.93 g/cm³.

Why Iodine Matters

The element that keeps your thyroid healthy and wounds clean

In Your Home

  • Iodized salt (prevents goiter)
  • Antiseptic solutions (iodine/Betadine)
  • Contrast dye for medical imaging
  • Water purification tablets

Industry Uses

MedicalContrast agents for X-rays and CT scans
NutritionIodized salt prevents iodine deficiency worldwide
NuclearRadioactive I-131 treats thyroid cancer
PhotographySilver iodide in traditional film (historical)

In Your Body

✓ Essential for life

Essential for thyroid hormones (T3, T4) that regulate metabolism. Deficiency causes goiter and developmental problems. Your body contains about 20mg.

Safety: Excess iodine can cause thyroid problems. Concentrated iodine solutions irritate skin. Radioactive I-131 requires careful handling.

Discovery of Iodine

Discovered by Bernard Courtois in France, 1811

Name origin: Greek: iôeides (violet colored).

History & Events

1811
Discovery
Bernard Courtois discovered iodine in seaweed ash while making saltpeter for Napoleon's army
1924
Iodized Salt
US introduced iodized salt, dramatically reducing goiter rates
1946
Medical Isotope
I-131 first used to treat thyroid cancer, pioneering nuclear medicine

About Iodine

Dark violet nonmetallic element, belongs to group 17 of the periodic table. Insoluble in water. Required as a trace element for living organisms. One stable isotope, I-127 exists, in addition to fourteen radioactive isotopes. Chemically the least reactive of the halogens, and the most electropositive metallic halogen. Discovered in 1812 by Courtois.

Atomic Properties of I

Atomic Number of I
53
Atomic Mass of I
126.9000 u
Electron Configuration
[Kr] 4d10 5s2 5p5
Electronegativity
2.66
Block
p-block
Group
17
Period
5

Physical Properties of I

Phase (STP)
solid
Melting Point of I
386.85 K
Boiling Point of I
457.40 K
Density of I
4.9330 g/cm3

Thermal Properties

Heat of Fusion
15.52 kJ/mol
Heat of Vaporization
41.95 kJ/mol
Specific Heat
0.21 J/g·K
Molar Heat Capacity
54.43 J/mol·K

Atomic Radii

Calculated
140 pm
Covalent
133 pm
Van der Waals
198 pm

Common Misconceptions

Wrong:All salt contains iodine.
Correct:Only iodized salt has added iodine. Sea salt, kosher salt, and specialty salts usually don't.
Wrong:Iodine is only for wounds.
Correct:Dietary iodine is essential! Iodine deficiency is the world's leading cause of preventable intellectual disability.
Wrong:You can get enough iodine from seafood.
Correct:Unless you eat seafood very regularly, you may need iodized salt or other sources.

Isotopes of Iodine

Iodine has 1 naturally occurring isotope, plus 5 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
12353I (I-123)Iodine-123 isotope122.9055890%13.2 hoursEC
12453I (I-124)Iodine-124 isotope123.90620990%4.18 daysEC, β⁺
12553I (I-125)Iodine-125 isotope124.90463020%59.4 daysEC
12753I (I-127)Iodine-127 isotope126.9044719100.00%
12953I (I-129)Iodine-129 isotope128.9049880%15.7 million yearsβ⁻
13153I (I-131)Iodine-131 isotope130.90612460%8.02 daysβ⁻

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Selected uses of notable Iodine isotopes.

I-123

Thyroid imaging; brain perfusion SPECT; cardiac imaging

I-124

PET imaging; thyroid cancer dosimetry; quantitative imaging

I-125

Brachytherapy seeds for prostate cancer; laboratory tracers; RIA assays

I-129

Environmental tracer; nuclear waste indicator; cosmogenic dating

I-131

Thyroid cancer treatment and imaging; nuclear fallout concern

Applications reference: IUPAC Isotopes Matter and NIH PubChem.

Abundance

Earth's Crust
450.00 μg/kg
Seawater
60.00 μg/kg

Uses

Required in small amounts by humans. Widely used as an antiseptic, for example as povidone-iodine (Betadine) and tincture of iodine.

Occurrence and Production

Occurs on land and in the sea in sodium and potassium compounds.

Geochemistry

Goldschmidt
litophile
Geochemical Class
semi-volatile

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