Periodic Table

Argon

Noble Gas

Quick Facts about Argon

Cl
  • gas- state of matter at room temperature
  • Stable- has at least one stable isotope
  • 0- common oxidation states in compounds
  • FCC- crystal structure, atomic arrangement in solid form
K

Argon (Ar) is element 18 on the periodic table. Atomic mass of Ar: 39.9480 u. Ar is in period 3, group 18. Melting point of Ar: 83.81 K.Density of Ar: 0.00 g/cm³.

Why Argon Matters

The invisible shield that protects everything from light bulbs to wine

In Your Home

  • Inside every incandescent and fluorescent light bulb
  • Double-pane windows (argon insulation)
  • Wine preservation systems
  • Some fire extinguishers

Industry Uses

WeldingShielding gas prevents oxidation during TIG and MIG welding
LightingFills incandescent bulbs to prevent filament oxidation
FoodDisplaces oxygen in wine bottles and food packaging
SteelInert atmosphere for producing high-purity metals

In Your Body

✗ Not essential

No biological function. You inhale argon with every breath (0.93% of air) and exhale it unchanged.

Safety: Non-toxic. At high concentrations can cause asphyxiation. Used safely in food preservation.

Discovery of Argon

Discovered by Sir William Ramsay, Baron Rayleigh in England, 1894

Name origin: Greek: argos (inactive).

History & Events

1894
Discovery
Lord Rayleigh and William Ramsay discovered argon after noticing nitrogen from air was denser than nitrogen from chemicals
1904
Nobel Prize
Rayleigh and Ramsay won Nobel Prizes (Physics and Chemistry) for discovering argon
1957
Argon Dating
Potassium-argon dating developed, enabling dating of rocks millions of years old

About Argon

Monatomic noble gas. Makes up 0.93% of the air. Colorless, odorless. Is inert and has no true compounds. Lord Rayleigh and Sir william Ramsey identified argon in 1894.

Atomic Properties of Ar

Atomic Number of Ar
18
Atomic Mass of Ar
39.9480 u
Electron Configuration
[Ne] 3s2 3p6
Electronegativity
Block
p-block
Group
18
Period
3

Physical Properties of Ar

Phase (STP)
gas
Melting Point of Ar
83.81 K
Boiling Point of Ar
87.30 K
Density of Ar
0.0018 g/cm3

Thermal Properties

Heat of Vaporization
6.52 kJ/mol
Specific Heat
0.52 J/g·K
Molar Heat Capacity
20.79 J/mol·K
Thermal Conductivity
0.02 W/m·K

Atomic Radii

Calculated
71 pm
Covalent
96 pm
Van der Waals
188 pm

Common Misconceptions

Wrong:Argon is rare.
Correct:Argon is the 3rd most abundant gas in Earth's atmosphere at 0.93%, more common than CO⁠2!
Wrong:Noble gases never form compounds.
Correct:While argon is very unreactive, heavier noble gases (Kr, Xe) can form compounds under extreme conditions.
Wrong:Argon-filled windows are a gimmick.
Correct:Argon is 34% less thermally conductive than air, providing real energy savings in double-pane windows.

Isotopes of Argon

Argon has 3 naturally occurring isotopes, plus 3 notable radioactive isotopes.

IsotopeAtomic Mass (u)AbundanceHalf-LifeDecay Mode
3618Ar (Ar-36)Argon-36 isotope35.96754510.3336%
3718Ar (Ar-37)Argon-37 isotope36.96677590%35 daysEC
3818Ar (Ar-38)Argon-38 isotope37.962732110.0629%
3918Ar (Ar-39)Argon-39 isotope38.96431310%269 yearsβ⁻
4018Ar (Ar-40)Argon-40 isotope39.9623831299.60%
4118Ar (Ar-41)Argon-41 isotope40.96450060%109.6 minutesβ⁻

Data source: NIH PubChem (aggregated from IUPAC, NIST)

Isotope Applications

Selected uses of notable Argon isotopes.

Ar-37

Neutrino detection experiments; underground science

Ar-39

Groundwater dating; ocean circulation tracer

Ar-40

K-Ar dating of rocks and minerals

Ar-41

Produced in nuclear reactors; atmospheric tracer

Applications reference: IUPAC Isotopes Matter and NIH PubChem.

Abundance

Earth's Crust
3.5 mg/kg
Seawater
450.00 μg/kg

Uses

Used in lighting products. It is often used in filling incandescent light bulbs. Some is mixed with krypton in fluorescent lamps. Crystals in the semiconductor industry are grown in argon atmospheres.

Occurrence and Production

Continuously released into the air by decay of radioactive potassium-40. Pure form is obtained from fractional distillation of liquid air.

Geochemistry

Goldschmidt
atmophile
Geochemical Class
volatile

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