Atomic Properties of As
- Atomic Number of As
- 33
- Atomic Mass of As
- 74.9220 u
- Electron Configuration
- [Ar] 3d10 4s2 4p3
- Electronegativity
- 2.18
- Block
- p-block
- Group
- 15
- Period
- 4
Arsenic (As) is element 33 on the periodic table. Atomic mass of As: 74.9220 u. As is in period 4, group 15. Melting point of As: 1090.00 K.Density of As: 5.73 g/cm³.
Arsenic in everyday life and industry
Some organisms have evolved arsenic tolerance Arsenic contamination in groundwater affects millions worldwide, especially in Bangladesh
Discovered by Known to the ancients.,
Name origin: Greek: arsenikon; Latin: arsenicum, (both names for yellow pigment).
Metalloid element of group 15. There are three allotropes, yellow, black, and grey. Reacts with halogens, concentrated oxidizing acids and hot alkalis. Albertus Magnus is believed to have been the first to isolate the element in 1250.
Arsenic exists in 3 different structural forms (allotropes), each with unique properties.
Most common and stable form, metallic appearance
Soft, waxy, unstable form
Amorphous form
Arsenic has 1 naturally occurring isotope, plus 2 notable radioactive isotopes.
| Isotope | Atomic Mass (u) | Abundance | Half-Life | Decay Mode |
|---|---|---|---|---|
| 7233As (As-72)Arsenic-72 isotope | 71.926752 | 0% | 26 hours | β⁺, EC |
| 7433As (As-74)Arsenic-74 isotope | 73.9239286 | 0% | 17.8 days | β⁺, EC, β⁻ |
| 7533As (As-75)Arsenic-75 isotope | 74.92159457 | 100.00% | — | — |
Data source: NIH PubChem (aggregated from IUPAC, NIST)
Isotopes of Arsenic have important real-world applications in science and industry.
72As (with a half-life of 26 h) and 74As are useful in molecular imaging because they are radioactive isotopes that emit positrons that can be designed to bind to monoclonal antibodies (moAb), which accumulate in tumors and then 72As- or 74As-labeled ligands will bind to the moAbs. Once the 72As- or 74As-labeled ligand binds to the moAb, positron emission tomography (PET) is used to visualize the exact location of the tumor [272]. A specific example of using radiolabeled antibodies for better imaging of tumors is the combination of 74As with bavituximab, which is an antibody that binds strongly to unique lipids on the surface of tumors. When a thiol group is introduced to bavituximab, arsenic is able to bind covalently, creating a simple and elegant radio-label for targeting cancerous tumors [269].
Many of its compounds are deadly poison and used as weed killer and rat poison. Conducts electricity. Used in semiconductors. Some compounds, called arsenides, are used in the manufacture of paints, wallpapers, and ceramics.
Found in mispickel (arsenopyrite)
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